Науково-дослідна лабораторія "Науки про Землю"

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Browsing Науково-дослідна лабораторія "Науки про Землю" by Subject "chlorides"

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    Anthropogenic impact of the war on the condition of surface waters of the rivers Kazennyi Torets and Kryvyi Torets within the city of Druzhkivka
    (2025) Horoshkovа, Lidiia; Menshov, Oleksandr; Nekos, Alla; Korniichuk, Yuliia; Khaduskina, Kateryna
    Purpose. To provide a comprehensive ecological assessment of the surface waters state of the Kryviy Torets and Kazenny Torets rivers in the city of Druzhkivka in order to determine the main anthropogenic factors of influence, in particular the consequences of war. Methods. System analysis, statistical processing methods, analysis of retrospective dynamics, and forecasting of future trends. Results. An analysis of water condition indicators was carried out for the monitoring posts – Kryvyi Torets River and Kazennyi Torets River. Organic pollution (BOD₅ and dissolved oxygen) in both rivers throughout the entire observation period there was a systematic excess of BOD₅ over the MPC. The concentration of dissolved oxygen repeatedly dropped below the standard, which indicates a threat to aquatic biota and disruption of selfpurification processes. Nitrites constantly and significantly exceeded the standard, especially in 2005–2008. Periodic significant maxima of phosphate-ion content were recorded, which indicates eutrophication processes and the inflow of phosphates from detergents and fertilizers. Water mineralization (sulfate and chloride ions) is high, especially in 2006–2008 and 2011–2013. Since 2014, stabilization has been observed, but at a high level. Using the Forecast Sheet resource forecasting carried out, which showed good convergence of forecast and actual values. No positive dynamics in water quality were recorded — in 2024–2025 most indicators exceed the MPC. Conclusions. The rivers Kazennyi Torets and Kryvyi Torets are in a state of persistent organic and chemical pollution. The overall ecological condition remains unsatisfactory, and in 2024–2025 the situation has even worsened. Overall, the war has significantly deepened the ecological problems of these rivers. They require a comprehensive approach to restoration: modernization of treatment facilities, rehabilitation of aquatic ecosystems, and restoration of the monitoring system. Without this, there is a threat of further degradation of the region’s water resources, which will have long-term consequences for the environment and human health.
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    Ecological Assessment of Surface Water Conditions of the Danube River
    (2025) Horoshkova, Lidiіa; Menshov, Oleksandr; Korniichuk, Yuliia; Horoshkov, Stanislav; Ryshykov, Igor
    Purpose. To provide a comprehensive environmental assessment and forecasting of the condition of surface waters of the Danube River within the Ukrainian section (Reni – Izmail – Vylkove), with a focus on the dynamics of key hydrochemical indicators over the period 2010–2024. Special attention is given to the influence of anthropogenic factors, including intensive navigation, industrial pressure, and the environmental consequences of military actions, which have altered the hydrological regime and deteriorated water quality. Methods. System analysis, statistical data processing, distribution analysis, and regression modeling were employed to assess retrospective dynamics and predict future trends in water quality. The information was sourced from long-term monitoring data collected at observation stations in the cities of Kiliya, Vylkove, and the river’s mouth. Results. The analysis focused on six key water quality indicators: phosphates, ammonium, sulfates, chlorides, biochemical oxygen demand over five days (BOD₅), and dissolved oxygen concentration. Phosphate and ammonium compounds exhibited seasonal fluctuations, attributed to discharges of organic and agricultural origin. Sulfate concentrations were found to be highly variable, combining both natural and anthropogenic sources, while chloride levels remained stable with signs of chronic influence. The analysis of BOD₅ and dissolved oxygen indicators suggests a potential for self-purification, although certain periods revealed deterioration in oxygen balance, particularly due to localized organic overload and disrupted hydrodynamics. Developed regression models allowed the identification of relationships between hydrological changes, port activity intensity, and pollution levels.Conclusions. The main environmental issues of the lower Danube were identified as organic and mineral pollution, eutrophication, decreased oxygen levels, hydromorphological changes, and threats posed by armed conflict. Despite these challenges, the river retains a capacity for partial self-recovery, especially under reduced anthropogenic pressure. Restoring ecological balance will require the implementation of systematic monitoring, modernization of wastewater treatment facilities, effective pollution source management, and Ukraine’s active participation in international environmental regulatory mechanisms, such as the Danube Commission. The modeling results can be used to forecast water environment conditions in both peacetime development and post-war recovery scenarios.